ot be created or destroyed, only transferred or converted. For a control mass: Change in internal energy = Heat added – Work done by the system Mathematically: ΔU = Q – W This law underpins the analysis of energy exchanges
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steps, each with its own rate expression. Elementary steps include: Unimolecular decompositions Bimolecular collisions Radical chain processes Mechanistic considerations: The rate-determining step controls the overall reaction rate. Intermedi
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